Characterizing N2O emissions from WWTPs
- Nitrous oxide (N2O) is a well known greenhouse gas produced and released in the biological sections of wastewater treatment plants (WWTPs)
- Due to the significant contribution to the carbon footprint of WWTPs, various attempts are currently being made to monitor and minimize N2O emissions, also through dedicated regulation
- Multiple studies have addressed N2O emissions from full scale WWTPs employing different treatment technologies and operational modes focusing on medium and large sized WWTPs
- Considerably less information is available for small sized WWTPs (< 20,000 PE), which in Denmark represent 16% to the overall treatment capacity
The objective of the study was to evaluate the importance on N2O emissions from both main and sidestream treatment processes of
- WWTP size and/or capacity
- Operational mode of bioreactors (continuous flow, sequencing batch)
- Aeration systems (bottom and surface aerators)
- Temporary changes and transient conditions in the operation of WWTPs
A measuring campaign was conducted to monitor N2O emissions from three different WWTPs managed by the same utility (Fors A/S, Denmark)
When: June to September 2021 for a period of 14 days in each WWTPs
How: Two N2O Wastewater Sensors from Unisense Environment were used to measure N2O concentrations in the water phase and emissions to the gas phase were estimated based on the supplier’s recommendations. A transportable sensor setup was employed, with a monitoring suitcase containing a mini pc that could be accessed remotely (Figure 1). Data was collected and stored in DIMS CORE (DHI A/S, Denmark) installed on the mini pc to avoid setup in SCADA. N2O emissions were monitored in three municipal WWTPs.
Where (Figure 2):
- Bjergmarken WWTP (125,000 PE) includes biological treatment with BioDeniphoTM configuration. N 2 O sensors were placed in two aerated tanks (LT2 and LT3) of parallel lines.
- Holbæk WWTP (60,000 PE) includes five parallel treatment lines operated in sequencing-batch reactor (SBR) mode with alternating anoxic and aerated phases and sidestream treatment of reject water with ANITATM Mox. N 2 O sensors were placed in two parallel sequencing batch reactors (SBR4 and SBR5) and in the ANITATM Mox reactor.
- Hvalsø WWTP (11,570 PE) and includes biological treatment with pre-denitrification and nitrification, whereby oxygen is supplied through surface aerators. N 2 O sensors were placed before and after surface aerators.
Results & Discussion
High variability in N2O emissions was observed during the monitoring campaign (Figure 3). Very high N2O emissions were measured in the first part of the monitoring campaign and were associated to temporary changes in process operation (namely inlet pumping, and aeration set points). After stable operation was achieved, short periods of elevated N2O emissions could still be detected. Overall, elevated emissions were observed in less than 10 of the monitoring time, leading to significant differences in emission factors calculated by considering (0.8% N2O-N/N removed) and neglecting (0.4%) unusually high emissions.
N2O emissions in the two SBR tanks differed by a factor 4. Phase length can result in uneven load concentrations in the tanks and can thus lead to diverting N2O emissions. Strategies of load equalization could minimize emissions. Interestingly, low N2O emissions from ANITATM Mox were observed (0.7-0.8%) as compared to other reject water treatment systems (e.g., 5.5% for DEMON). Continuous aeration and inflow, together with the use of biofilm systems, can be thus hypothesized as strategies for emission reduction in sidestream treatment.
Monitoring results indicated considerably low N2O emissions (0.00005% N2O-N/N removed). This observation is of relevance to assess strategies supporting centralized treatment in medium and large sized WWTPs.
The overall results from the monitoring campaign, including calculated N2O emission factors for main and sidestream processes in the three WWTPs, are summarized in Table 1.